Химия

A mathematical model of the adsorber was developed using the Toth equation. Microporous mordenite was synthesized to confirm model validation. The structure and characteristics of the obtained sorbent were confirmed by SEM, N2 adsorbtion, XRD and XRF methods. Adsorption of the hydrogen-methane mixture on H-form of synthesized mordenite was carried out at the pressure of 2 MPa and the temperature range of 20–35 °С.

The possibility of obtaining asymmetric 1,5-diketones based on 4-hydroxy-2H-chromen-2-one and dimedone by three-component condensation in the presence of L-proline as a catalyst is shown. As a result, a series of 4-hydroxy3 - ((2-hydroxy-4,4-dimethyl-6-oxocyclohex1-en-1-yl) (aryl) methyl) -2H-chromen-2-ones was obtained with a yield of 25 up to 73%. The study revealed that the highest yield was observed for compounds containing fragments of ortho-substituted aldehydes capable of forming a hydrogen bond. For meta- and para-substituted – the lowest yield was observed.

The paper presents the results of optimizing the conditions for the chromatographic determination of 2,4-dichlorophenoxyacetic acid and deltamethrin for two capillary columns (Supelcosil LC-18, Kromasil C-18). The modes of individual chromatography of pesticides were selected. The use of the isocratic elution mode in the joint presence of 2,4-dichlorophenoxyacetic acid and deltamethrin was shown and experimentally proved to be invalid. Three options were proposed for the conditions of the gradient mode of the separate detection of analytes in a mixture.

A comprehensive method for meldonium analysis, based on a combination of magnetic solid-phase concentration of the analyte on magnetite nanoparticles modified with cetylammonium bromide (CTAB) cations and its subsequent analysis by thin-layer chromatography (TLC) were developed in the process of study. The influence of a number of factors on meldonium sorption was studied, namely: pH, sorbent mass, sorption and mixing times; optimal extraction conditions were determined.

The results of the study of the morphology and surface topography of chitosan films of the salt (S-) and basic (B-) chemical form by atomic force microscopy are presented. The films were cast from polymer solutions in acetic, lactic, citric and succinic acid. NaOH and triethanolamine were used for the salt > chitosan base reaction. Surface tomograms were obtained; the main morphological characteristics and roughness parameters of the film samples were estimated.

. Electroanalytical properties of unmodified and modified by polyaniline and by CuO nanoparticles solid-contact potentiometric sensors which are based on associates of tetradecylammonium with complex compounds of silver (I) with cephuroxime, cephotaxime and cephazoline Ag(?-lac)2TDA in solutions of corresponding antibiotics were studied. It was revealed that Ag(?-lac)2TDA –based sensors had no specificity to the basic ion but showed sensitivity to other cephalosporins.

The search and the analysis of English scientific literature from 2005 to 2020 devoted to the methods of obtaining branched polymers and copolymers of N-isopropylacrylamide were made in order to obtain novel materials with valuable properties. It was found that modern methods of controlled radical polymerization were mainly used for this purpose, namely, atom transfer radical polymerization (ATRP), polymerization with reversible addition-fragmentation chain transfer (RAFT) and group transfer polymerization (GTP).

The effective nanostructured sorbents based on natural bentonite modified with aluminum and iron (III) polyhydroxocations were obtained. The elemental composition of the obtained sorbents was studied. The specific surface area was determined for the studied samples. It was shown that modified sorbents based on natural bentonite were nanostructured objects. IR spectroscopy showed that modification of natural bentonite led to the changes in its structural properties.

Complexing of nickel(II) with 2,6-dimercapto-4-methylphenol (DMMP) and hydrophobic amines was studied using physicochemical methods. Hydroxyl-containing amines-aminophenols (AP) were used as a hydrophobic amine. On the part of aminophenols, 2 (N, N-dimethylaminomethyl) -4-methylphenol (AP1 ), 2 (N, N-dimethylaminomethyl)-4-chlorophenol (AP2 ), and 2 (N, N-dimethylaminomethyl) -4-bromophenol (AP3 ) were used. Mixed-ligand complexes were formed in a weakly acidic medium (pHopt 4.6–6.4).

The phase diagram of the ?-alanine–water binary system was studied using the visual polythermal method and the method of time–temperature curves in а temperature range of -20–90°С. There is a eutectic equilibrium at -18.3°С in the system; the solid phases of this equilibrium are ice and individual ?-alanine. For the first time, the composition of the liquid phase of the eutectic state was determined.