Izvestiya of Saratov University.

Chemistry. Biology. Ecology

ISSN 1816-9775 (Print)
ISSN 2541-8971 (Online)
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Language: 
Russian
Heading: 
Chemistry
Article type: 
Article
UDC: 
544.344.016+536.445:544.344.013-16-14+66.061
DOI: 
10.18500/1816-9775-2021-21-2-159-168
EDN: 
XURSVV

Extractive crystallization of salts in the ternary systems sodium (potassium, cesium) nitrate – water – triethylamine

Autors: 
Danilina Veronika V., Saratov State University
Chernov Dmitriy I., Saratov State University
Cherkasov Dmitry G., Saratov State University
Il’in Konstantin Kuzmich, Saratov State University
Abstract: 

A comparative analysis of the results of our polythermal study of the ternary systems sodium (potassium, cesium) nitrate – water – triethylamine has been carried out to estimate the efficiency of the use of triethylamine in the extractive crystallization of alkali metal nitrates from water–salt solutions containing 43.0, 44.0, 45.0, 46.0, and 47.0 wt. % sodium nitrate in the range of 10.0–25.0°C, 20.0, 21.0, and 22.0 wt.% potassium nitrate and 18.0, 19.0, 20.0 and 21.0 wt. % cesium nitrate in the range of 20.0–25.0°C. The dependences of the yield of these salts on the amount of triethylamine added and temperature have been found. It has been established that the maximum yield of sodium nitrate (79.4%) is observed for the aqueous solution with 47 wt.% salt upon the introduction of 90 wt.% triethylamine at 25.0° C. The maximum yield in the systems potassium (cesium) nitrate – water – triethylamine was 68.9% (22 wt. % potassium nitrate solution) and 66.2% (21 wt. % cesium nitrate solution) at 20.0° C and 90 wt. % amine content.

Key words: 
solubility
salt production
salting out
phase equilibria
liquid-liquid equilibrium
monotectic equilibrium
alkali metal nitrates
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Received: 
19.01.2021
Accepted: 
08.02.2021
Published: 
30.06.2021