For citation:
Pchelintseva N. V. Heterocyclization Peculiarities of Dichloropentene- and Dichloropentanediones with Nucleophilic Reagents. Izvestiya of Saratov University. Chemistry. Biology. Ecology, 2008, vol. 8, iss. 1, pp. 3-7.
Heterocyclization Peculiarities of Dichloropentene- and Dichloropentanediones with Nucleophilic Reagents
Own research results of the structure and heterocyclizations of the alkylarylsubstituted 2,4-dichloro-2-pentene- and 2,4-dichloropentane-1,5-diones were summarized. Dichlorosubstituted pentenedi-ones and there saturated analogs turn out different transformations in the reactions with the same reagents have been founded. The possibility of obtaining of N-containing cyclic compounds with different chlorine containing in the structure are shown. Probable schemes of benzolichloro- pyrrols, mono- and dichloropyridines forming have been proposed.
- Харченко В.Т., Чалая С.Н. 1,5-дикетоны. Саратов: Изд-во Сарат. ун-та, 1977. С.42-72.
- Пчелинцева Н.В., Чалая С.Н., Харченко ВТ. Нуклеофильные реакции арилзамещенных 2,4-дихлор-2-пентен-1,5-дионов//ЖОрХ. 1990. Т.26, вып.9. С.1904-1908. EDN: YMSUUH
- Kharchenko V.G., Chalaya S.N., Litvinov O.V., Pchelintse-va N. V. Azaheterocyclisation of chlorosubstitited carbonyl compounds//9th symposium on the chemistry of heterocyclic compounds: Abstracts. Bratislava, 1987. P. 197.
- Kharchenko V.G., Chalaya S.N., Litvinov O. V. et al. Synthesis and biological activity of benzoylpyrrols, chloropyridines and isoindoles//5th IECHEM conference on heterocycles in bioorganic chemistry: Abstracts. Praga, 1988. P.206.
- Харченко В.Т., Чалая С.Н., Литвинов О.В. Взаимодействие α,α'-дихлорзамещенных 1,5-дикетонов с аммиаком и ацетатом аммония//ХГС. 1985. №3. С.352-354.
- Greenhill J. V., Mohamed I.M. Reactions between enaminones and enons//J. Chem. Soc. Perkin Trans. 1979. P.I, №6. P.1411-1414.
- Weiss M. Acetic acid ammonium acetate reactions//J. Amer. Chem. Soc. 1952. Vol.74, №1. P.200-202.
- Общая органическая химия/Под ред. Д. Бартона и У.Д. Оллиса. М.: Химия, 1982. Т.З. С.32-95.
- Пчелинцева Н.В., Харченко В.Т., Чалая С.Н., Сорокин Н.Н. Стереохимические особенности арилзамещенных 2,4-ди-хлор-2-пентен-1,5-дионов//ЖОрХ. 1994. Т.30, вып.4. С.321-324.
- Литвинов О.В., Комягин И. Т., Чалая С.Н. и др. Синтез и молеклярная структура 3-метил-1,5-дифенил-2,4-дихлор-1,5-пентадиона//ЖОрХ. 1989. Т.25, вып.1. С.34-39.