Izvestiya of Saratov University.

Chemistry. Biology. Ecology

ISSN 1816-9775 (Print)
ISSN 2541-8971 (Online)


Full text:
(downloads: 17)
Language: 
Russian
Heading: 
Article type: 
Article
UDC: 
543.42.062:546.74

Investigation of nikel(II) complexing with 2,6-dimerkapto-4-methilphenol and aminophenols

Autors: 
Kuliev K. А., Azerbaijan State Pedagogical University
Mamedova Shafa A., Azerbaijan State Pedagogical University
Efendiyeva Naiba N., Azerbaijan State Pedagogical University
Abstract: 

Complexing of nickel(II) with 2,6-dimercapto-4-methylphenol (DMMP) and hydrophobic amines was studied using physicochemical methods. Hydroxyl-containing amines-aminophenols (AP) were used as a hydrophobic amine. On the part of aminophenols, 2 (N, N-dimethylaminomethyl) -4-methylphenol (AP1 ), 2 (N, N-dimethylaminomethyl)-4-chlorophenol (AP2 ), and 2 (N, N-dimethylaminomethyl) -4-bromophenol (AP3 ) were used. Mixed-ligand complexes were formed in a weakly acidic medium (pHopt 4.6–6.4). Ni(II) is recovered by chloroform by 98.6–99.5% in the form of a mixed-ligand complex (MLC) per single extraction. The optimal conditions for the formation and extraction of these compounds are 1.12 ? 10-3 mol/L concentration of DMMP and 0.88 ? 10-3 mol/L – AP. Changing the concentration of the reagents does not change the composition of the complexes. MLC of Ni(II) with DMMP and AP are stable in aqueous and organic solvents and do not decompose within three days and for more than a month after extraction. The ratio of reacting components in MLC corresponds to Ni (II): DMMP : AP = 1 : 2 : 2. in the formation of MLC, the coordinating ion is Ni2+. Complexing proceeds with the displacement of a proton from a DMMP molecule. Maximum light absorption is observed at ? = 520–530 nm. The molar coefficients of light absorption are (3.78-3.95) ? 104 . Based on the obtained data photometric methods for the determination of nickel in various industrial and natural objects were developed.

Reference: 
  1. Sadovnikova L. K., Orlov D. S., Lozanovskaya I. N. Ekologiya i okhrana okruzhayushchey sredy pri khimicheskom zagryaznenii [Ecology and environmental protection during chemical pollution]. Moscow, Vysshaya shkola Publ., 2006. 334 p. (in Russian).
  2. Avci H., Kaya G., Akdeniz I., Ince M., Yaman M. Flame atomic absorp ti on spec tro metric determination of nickel and chromium in various plant leaves used as bi omonitors in environmental pollution. Fresenius Environmental Bulletin, 2013, vol. 22, no. 2, pp. 379–387.
  3. Dobrowolski R., Otto M. Determination of nickel and cobalt in reference plant mate rials by carbon slurry sampling GFAAS technique after their simultaneous preconcentration onto modifi ed activated carbon. Journal of Food Composition and Analysis, 2012, vol. 26, no. 1–2, pp. 58–65.
  4. Sadeghi O., Tavassoli N., Amini M. M., Ebrahimzadeh H., Daei N. Pyridine-fun ctio nalized mesoporous silica as an adsorbent material for the determination of nickel and lead in vegetables grown in close proximity by electrothermal atomic adsorption spec troscopy. Food Chemistry, 2011, vol. 127, no. 1, pp. 364–368.
  5. Zeng C., Jia Y., Lee Y. I., Hou X., Wu L. Ultrasensitive determination of cobalt and nickel by atomic fl uorescence spectrometry using APDC enhanced chemical vapor generation. Microchemical Journal, 2012, vol. 104, pp. 33–37.
  6. Beiraghi A., Babaee S., Roshdi M. Simultaneous preconcentration of cadmium, cobalt and nickel in water samples by cationic micellar precipitation and their determination by in ductively coupled plasma-optical emission spectrometry. Microchemical Journal, 2012, vol. 100, pp. 66–71.
  7. Marchenko Z., Bal’tsezhak M. K. Metody spektrofotometrii v UF i vidimoy oblastyakh v neorganicheskom analize [Spectrophotometry methods in the UV and visible regions in inorganic analysis]. Moscow, Binom. Laboratoriya znaniy Publ., 2007. 711 p. (in Russian).
  8. Kornev V. I., Shadrina L. S. Complexation of transition metals with ?-ketoglutaric acid in aqueous solution. Bulletin of the Udmurt University. Series 4: Physics and Chemistry, 2010, no. 2, pp. 43–47 (in Russian).
  9. Shabani A. M. H., Dadfarnia S., Shahbaazi Z., Jafari A. A. Extraction-spectrophotometric de ter mination of nickel at microgram level in water and wastewater using 2-[(2-mercapto pheny limi no) methyl]phenol. Bull. Chem. Soc. Ethiop., 2008, vol. 22, no. 3, pp. 323–329.
  10. Xu L., Meng S., Liu Y., Fan Y. Guo Y., Wang J. Spectrophotometric determination of nickel in biological samples using 1-azobenzene-3-(3-hydroxyl-2-pyridyl)-triazene. Journal of Analytical Chemistry, 2008, vol. 63, no. 12, pp. 1269–1274.
  11. Aliyeva R. A., Mardanova V. I., Chyragov F. M. Complexation of nickel (II) with azo derivatives of chromotropic acid. Baku University News, 2009, no. 1, pp. 5–9 (in Russian).
  12. Terra L. H. S. A., Areias M. C. C., Gaubeura I., Suarezihaa M. E. V. Solvent Extraction-Spec tro phot ometric determination of nickel(II) in natural waters using di2-pyridyl ketone benzoylhyd ra zone. Spectroscopy letters: An international journal for rapid communication, 1999, vol. 32, no. 2, pp. 257–271.
  13. Ivanov V. M., Samarina T. O., Figurovskaya V. N. Optical and colorimetric characteristics of the complex of nickel (II) with 1-nitroso-2-naphthol-3, 6-disulfonic acid. Moscow University Chemistry Bulletin, 2011, vol. 52, no. 4, pp. 285–290 (in Russian).
  14. Domina G. A., Potapov A. S., Khlebnikov A. I., Tszide V. Synthesis of complexes of 1,3-bis (pyrazol-1-yl) propanes with transition metal ions. Polzunovsky vestnik, 2008, no. 3, pp. 10–13 (in Russian).
  15. Sarma L. S., Kumar J. R., Reddy K. J., Thriveni T., Reddy A. V. Development of highly sensitive extractive spectrophotometric determination of nickel(II) in medicinal leaves, soil, industrial effluentsand standard alloy samples using pyridoxal-4-phenyl-3-thiosemicarbazone. Journal of Trace Elements in Medicine and Biology, 2008, vol. 22, pp. 285–295.
  16. Pyatnitskiy. I. V., Trochinskaya G. N. Extraction of mixed phenanthroline-thiosalicylate complexes of iron (II), cobalt and nickel. Journal of Analytical Chemistry, 1973, vol. 28, no. 4, pp. 704–708 (in Russian).
  17. Rustamov N. Kh., Mustafayev N. M. Raznoligandnyy kompleks nikelya s 2,2-dipiridilom i dinitro benzolazosalitsilovoy kislotoy [Mixed-ligand complex of nickel with 2,2-dipyridyl and dinitrobenzene azosalicylic acid]. Organicheskiye reagenty v analiticheskoy khimii: tezisy dokladov 7-y Vseros. konf. [7th All-Russian Conference “Organic Reagents in Analytical Chemistry”]. Saratov, Izd-vo Sarat. un-ta, 1999, pp. 151 (in Russian).
  18. Chyragov F. M., Nagiyev Kh. D. Gambarov D. G. Izucheniye kompleksoobrazovaniye Ni(II) s novym reagentom na osnove pirokatekhina [Study of complexation of Ni (II) with a new reagent based on pyrocatechol]. Organicheskiye re agenty v analiticheskoy khimii: tezisy dokl. 7-y Vseros. konf. [7th All-Russian Conference "Organic Reagents in Analytical Chemistry"]. Saratov, Izd-vo Sarat. un-ta, 1999, pp. 140. (in Russian).
  19. Kornev V. I., Semonova M. G. Interaction of cobalt (II) and nickel (II) with complexones of a number of carboxymethyleneamines and malonic acid in aqueous solution. Bulletin of the Udmurt University. Series 4: Physics and Chemistry, 2010, no. 1, pp. 34–41 (in Russian).
  20. Aliyeva R. A., Nazarova G. G., Aliyeva F. S., Mardanova V. I., Chyragov F. M. Spektrofotomet richeskoye issledovaniye kompleksoobrazovaniya nikelya(II) c 2,21,3,4-tetragidroksi-31-sul’fo-5-nitroazobenzolom v prisutstvii kationnykh poverkhnostno aktivnykh veshchestv [Spectrophotometric study of the complexation of nickel (II) with 2,21,3,4-tetrahydroxy-31-sulfo-5-nitroazobenzene in the presence of cationic surfactants]. III Vseros . nauch. konf. (s mezhdunar. uchasti-yem): “Uspekhi sinteza i komplekso obra zovaniya” Konferentsiya posvyashchena 55-letiyu RUDN. [Achievements in synthesis and complexation: III All-Russian scientifi c conference (with international participation, dedicated to the 55th anniversary of RUDN]. Moscow, Russian University of Frendship of Peoples, 2014, pt. 2, pp. 126 (in Russian).
  21. Ravichandran C., Benzil D., Ramachandraiah C., Chandrasekhar K.B. Extraction and spectropho tometric determination of nickel in water, alloys and edible oil samples. International Journal of Bioassays, 2015, vol. 4, no. 11, pp. 4468–4472.
  22. Amin A. S., Al-Attas A. S. Study of the solid phase extraction and spectrophotometric de-termi na ti on of nickel using 5-(4-chlorophenylazo)-6-hydroxypyrimidine-2,4-dione in environmental samples. Journal of Saudi Chemical Society, 2012, vol. 16, no. 4, pp. 451–459.
  23. Ghaedi M. Selective and sensitized spectrophotometric determination of trace amounts of Ni(II) ion using ?-benzyl dioxime in surfactant media. Spectrochimica Acta Part A: Molecular and Biomo lecular Spectroscopy, 2007, vol. 66, no. 2, pp. 295–301.
  24. Zalov A. Z., Gavazov K. B. Extractive Spectrophotometric Determination of Nickel with 2-hydroxy-5-iodothiophenol and Diphenylguanidine. Chemistry Journal, 2014, vol. 4, no. 5, pp. 20–25.
  25. Kuznetsov V. V. Primeneniye organicheskikh analiticheskikh reagentov v analize neorganicheskikh veshchestv [Application of organic analytical reagents in the analysis of inorganic substances]. Moscow, MKHTI, 1972 . 145 p. (in Russian).
  26. Kuliyev K. A. Spectrophotometric study of nickel (II) complexes with 2, b-dithiol-h-ethylphenol and heterocyclic diamines. “Kost-20015”: International Congress on Heterocyclic Chemistry: Book of abstracts. Moscow, Moscow State University, 2015, pp. 457.
  27. Korostelev P. T. Prigotovleniye rastvorov dlya khimikoanaliticheskikh rabot [Preparation of solutions for chemical analytical work]. Moscow, Izd-vo AN SSSR, 1964. 401 p. (in Russian).
  28. Bulatov M. I., Kalinkin I. P. Prakticheskoye rukovodstvo po fotokolorimetricheskim i spektro fo tome tricheskim metodam analiza [A practical guide to photocolorimetric and spectrophotometric methods of analysis]. Leningrad, Khimiya Publ., 1986. 432 p. (in Russian).
  29. Nakamato K. IK-spektry i spektry KR neorganicheskikh i koordinatsionnykh soyedineniy [Infrared and Raman Spectra of Inorganic and Coordination Compounds]. Moscow, Mir Publ., 1991. 536 c. (in Russian).
  30. Bellami L. Infrakrasnyye spektry slozhnykh molekul [The Infrared Spectra of Complex Molecules]. Moscow, 1963. 592 p. (in Russian).
  31. Nazarenko V. A., Biryuk Ye. A. Study of the chemistry of the reactions of ions of multivalent elements with organic reagents. Journal of Analytical Chemistry, 1967, vol. 22, no. 1, pp. 57–64 (in Russian).
  32. Nazarenko V. A. Interaction of ions of multivalent elements with organic reagents. Transactions of the Commission for Analytical Chemistry of the USSR Academy of Sciences. Moscow, Nauka Publ., 1969, vol. 17, pp. 22–29 (in Russian).
  33. Akhmedli M. K., Klygin A. Ye., Ivanova L. I., Bashirov E. A. On the chemistry of the interaction of gallium ions with some sulfophthaleins. Russian Journal of Inorganic Chemistry, 1974, vol. 19, no. 8, pp. 2007–2012 (in Russian).
  34. Dorokhova Ye. N., Prokhorova G. V. Analiticheskaya khi miya (fiziko-khimicheskiye metody ana li za) [Analytical chemistry (physicochemical methods of analysis)]. Moscow, Vysshaya shkola Publ., 1991. 250 p. (in Russian).
  35. Yoshikuni N., Baba T., Tsunoda N., Oguma K. Aqueous two-phase extraction of nickel dime thyl glyoximato complex and its application to spectrophotometric determination of nickel in stainless steel. Talanta, 2005, vol. 66, no. 1, pp. 40–44.
  36. Ramachandraiah C., Kumar J. R, Reddy K. J. Development of a highly sensitive extractive spectrophotometric method for the determination of nickel(II) from environmental matrices using N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone. J. Environ. Manage, 2008, vol. 88, no. 4, pp. 729–736.
  37. Jadhav V. A, Kulkarni M. U. 7-Methl-2-chloroquinoline3-carbaldehyde thiosemicarbazone as ana ly tical reagentfor copper, cobalt and nickel (II). J. Indian. Chem. Soc., 1992, vol. 69, pp. 287–295.
  38. Otomo M., Watanabe T., Moriya M. Solvent Extraction and Spectrophotometric Determination of Nickel(II) with Thiazole-2-carbaldehyde 2-Quinolyl-hydrazone. Analytical Sciences, 1986, vol. 2, no. 6, pp. 549–552.
  39. Rekha D., Kumar J. D., Jayaraj B., Lingappa Y., Chiranjeevi P. Nickel(II) Determination by Spec trophotometry Coupled with Preconcentration Technique in Water and Alloy Samples. Bull. Korean Chem. Soc., 2007, vol. 28, no. 3, pp. 373– 378.
Received: 
01.03.2021