Izvestiya of Saratov University.

Chemistry. Biology. Ecology

ISSN 1816-9775 (Print)
ISSN 2541-8971 (Online)

For citation:

Pidenko S. ., Lovtsova L. G. Complex organomineral fertilizers and meliorants – a new eco-friendly approach to phosphogypsum utilization. Izvestiya of Saratov University. Chemistry. Biology. Ecology, 2023, vol. 23, iss. 2, pp. 166-174. DOI: 10.18500/1816-9775-2023-23-2-166-174, EDN: ARYPSH

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
download
(downloads: 135)
Полный текст в формате PDF(En):
download
(downloads: 34)
Language: 
Russian
Heading: 
Chemistry
Article type: 
Article
UDC: 
502.17:[631.619+631.895]
DOI: 
10.18500/1816-9775-2023-23-2-166-174
EDN: 
ARYPSH

Complex organomineral fertilizers and meliorants – a new eco-friendly approach to phosphogypsum utilization

Autors: 
Pidenko Sergey A., Saratov State University
Lovtsova Larisa G., Saratov State Agrarian University named after V.I. Vavilov.
Abstract: 

One of the modern approaches to solving environmental problems of accumulation and deposition of production and consumption waste is the implementation of “green economy” and “closed cycle” economy models. This approach makes it possible to increase the resource utilization rate and reduce the negative impact on the environment. The study of the possibility of joint disposal of waste from various industries, for example agricultural and industrial waste, is promising in this area. The analysis of the current state of work in this direction is carried out, using the example of the possibilities of joint utilization of phosphogypsum and organic waste. A new eco-friendly approach to the utilization of a large-tonnage secondary material resource – phosphogypsum together with organic waste is proposed. Phosphogypsum acts as a matrix for the production of complex organomineral fertilizers and meliorants of complex composition, the introduction of the organic component of fertilizers is carried out in the fi nished and neutralized liquid phase. Agricultural waste, municipal waste, s ewage sludge can be the raw materials for the organic component. The eff ectiveness of the complex organomineral fertilizer an d meliorant based on phosphogypsum (90% by weight) and the liquid fertilizer “Rabiol” with the inclusion of a highly selective sorbent based on molecular imprinted polymers to imazamox, a resistant herbicide of the imidazolinone class, is shown.

Key words: 
phosphogypsum
organomineral fertilizers
molecular imprinted sorbents
rabiol
imazamox
Reference: 
  1. Abad-Segura E., Batlles-dela Fuente A., GonzálezZamar M. D., Belmonte-Ureña L. J. Implications for sustainability of the joint application of bioeconomy and circular economy: A worldwide trend study // Sustainability. 2021. Vol. 13. P. 7182. https://doi.org/10.3390/su13137182
  2. 2. Галицкая П. Ю., Зверева П. А., Селивановская С. Ю. Совместная утилизация отходов различных производств с получением полезных продуктов и биогаза // Ученые записки Казанского университета. Серия Естественные науки. 2011. Т. 153, № 1. С. 152–160.
  3. Feng S., Yin Y., Yin Z., Zhang H., Zhu D., Tong, Y., Yang H. Simultaneously enhance iron/sulfur metabolism in column bioleaching of chalcocite by pyrite and sulfur oxidizers based on joint utilization of waste resource // Environ. Res. 2021, Vol. 194. P. 110702. https://doi.org/10.1016/j.envres.2020.110702
  4. Dieme M. M., Villot A., Gerente C., Andres Y., Diop S. N., Diawara, C. K. Sustainable conversion of agriculture wastes into activated carbons: Energy balance and arsenic removal from water // Environ. Technol. 2017. Vol. 38, № 3. P. 353–360. https://doi.org/ 10.1080/09593330.2016.1193225
  5. Sabir A., Altaf F., Batool R., Shafi q M., Khan R. U., Jacob K. I. Agricultural waste absorbents for heavy metal removal // Inamuddin Ahamed M., Lichtfouse E., Asiri A. (eds.). Green Adsorbents to Remove Metals, Dyes and Boron from Polluted Water. Environmental Chemistry for a Sustainable World. Vol. 49. Springer Cham., 2021. P. 195–228 https://doi.org/10.1007/978-3-030-47400-3_8
  6. Kumar V., Sharma N., Umesh M., Selvaraj M., Al-Shehri B. M., Chakraborty P., Duhan L., Sharma S., Pasrija R., Awasthi M. K., Lakkaboyana S. R., Andler R., Bhatnagar A., Maitra S. S. Emerging challenges for the agro-industrial food waste utilization: A review on food waste biorefinery // Bioresour. Technol. 2022. Vol. 49. P. 127790. https://doi.org/10.1016/j. biortech.2022.127790 
  7. Koul B., Yakoob M., Shah M. P. Agricultural waste management strategies for environmental sustainability // Environ. Res. 2022. Vol. 206. P. 112285. https://doi.org/10.1016/j.envres.2021.112285
  8. Donner M., Verniquet A., Broeze J., Kayser K., De Vries H. Critical success and risk factors for circular business models valorising agricultural waste and by-products // Resour. Conserv. Recycl. 2021. Vol. 165. P. 105236. https://doi.org/10.1016/j.resconrec.2020.105236
  9. Wei Z., Deng, Z. Research hotspots and trends of comprehensive utilization of phosphogypsum: Bibliometric analysis // J. Environ. Radioact. 2022. Vol. 242. P. 106778. https://doi.org/10.1016/j.jenvrad.2021.106778
  10. Chernysh Y., Yakhnenko O., Chubur V., Roubík H. Phosphogypsum recycling: a review of environmental issues, current trends, and prospects // Appl. Sci. 2021. Vol. 11, № 4. P. 1575. https://doi.org/10.3390/app11041575
  11. Wu F., Ren Y., Qu G., Liu S., Chen B., Liu X., Zhao C., Li J. Utilization path of bulk industrial solid waste: A review on the multi-directional resource utilization path of phosphogypsum // J. Environ. Manage. 2022. Vol. 313. P. 114957. https://doi.org/10.1016/j.jenvman.2022.114957
  12. Xiantao Q., Yihu C., Haowei G., Qisheng H., Zhihao L., Jing X., Hu B., Zhang Z., Rong L. Resource utilization and development of phosphogypsum-based materials in civil engineering // J. Clean Prod. 2023. Vol. 387. P. 135858. https://doi.org/10.1016/j.jclepro.2023.135858
  13. El Zrelli R., Rabaoui L., Daghbouj N., Abda H., Castet S., Josse C., van Beek P., Souhaut M., Michel S., Bejaoui M., Courjault-Radé P. Characterization of phosphate rock and phosphogypsum from Gabes phosphate fertilizer factories (SE Tunisia): High mining potential and implications for environmental protection // Environ. Sci. Pollut. Res. 2018. Vol. 25. P. 14690–14702. https://doi.org/10.1007/s11356-018-1648-4
  14. Cao J., Wang Z., Ma X., Yang X., Zhang X., Pan H., Wu J., Xu M., Lin L., Zhang Y., Xiao Y., Luo H. Promoting coordinative development of phosphogypsum resources reuse through a novel integrated approach: A case study from Chin // J. Clean Prod. 2022. Vol. 374. P. 134078. https://doi.org/10.1016/j.jclepro.2022.134078
  15. Mukaba J. L., Eze C. P., Pereao O., Petrik L. F. Rare earths’ recovery from phosphogypsum: An overview on direct and indirect leaching techniques // Minerals. 2021. Vol. 11, № 10. P. 1051. https://doi.org/10.3390/min11101051
  16. Антоненко Д. А., Никифоренко Ю. Ю., Мельник О. А. Особенности формирования сложного компоста на основе полуперепревшего навоза КРС и фосфогипса // Экологический вестник Северного Кавказа. 2019. Т. 15, № 4. С. 37–42.
  17. Zhantasov K., Ziyat A., Sarypbekova N., Kirgizbayeva K., Iztleuov G., Zhantasov M., Sagitova G., Aryn A. Ecologically friendly, slow-release granular fertilizers with phosphogypsum // Pol. J. Environ. Stud. 2022. Vol. 31, № 3. P. 2935–2942. https://doi. org/10.15244/pjoes/144099
  18. Akanova N. I., Vizirskaya M. M., Seregin M. B., Grebennikova T. V. The neutralized phosphogypsum as gypsumcontaining meliorant Russian case-study // Int. Agric. J. 2019. № 2. P. 12–18. https://doi.org/10.24411/2588-0209-2019-10048
  19. Wang X. J., Wang Z. Q., Li S. G. The effect of humic acids on the availability of phosphorus fertilizers in alkaline soils // Soil Use Manag. 1995. Vol. 11, № 2. P. 99–102. https://doi.org/10.1111/j.1475-2743.1995.tb00504.x
  20. Li H., Yang L., Cao J., Nie C., Liu H., Tian J., Chen W., Geng., Xie G. Water-preserving and salt-resistant slowrelease fertilizers of polyacrylic acid-potassium humate coated ammonium dihydrogen phosphate // Polymers. 2021. Vol. 13, № 17. P. 2844. https://doi.org/10.3390/ polym13172844
  21. Matveeva V. A., Smirnov Y. D., Suchkov D. V. Industrial processing of phosphogypsum into organomineral fertilizer // Environ. Geochem. Health. 2022. Vol. 44, № 5. P. 1605–1618. https://doi.org/10.1007/s10653-021-00988-x
  22. Бычкова В. В., Сазонова И. А., Пиденко П. С., Пиденко С. А., Бурмистрова Н. А. Негативные эффекты применения гербицидов группы имидазолинонов: проблемы и решения // Агрохимия. 2023. № 2. С. 99–108.
  23. Fu H., Xu W., Wang H., Liao S., Chen G. Preparation of magnetic molecularly imprinted polymers for the identifi cation of zearalenone in grains // Anal. Bioanal. Chem. 2020. Vol. 412. P. 4725–4737. https://doi.org/10.1007/ s00216-020-02729-y
  24. Buerge I. J., Bä chli A., Kasteel R., Portmann R., LópezCabeza R., Schwab L. F., Poiger T. Behavior of the chiral herbicide imazamox in soils: pH-dependent, enantioselective degradation, formation and degradation of several chiral metabolites // Environ. Sci. Technol. 2019. Vol. 53, № 10. P. 5725–5732. https://doi.org/10.1021/acs. est.8b07209
  25. Dischetti C., Scarponi L., Del Buono D. An analytical method for the determination of imazamox in soils and maize plants // Fresenius Environ. Bull. 2001. Vol. 10, № 2. P. 208–211.
  26. Соседенко Т. Ю., Пичугина А. С., Васькин С. М. Фосфогипс в качестве удобрения // Молодой ученый. 2020. № 47. С. 433–435.
  27. Жаппар Н. К., Шайхутдинов В. М., Мырзабаев Б. М., Зейнелов К. А., Шибаева А. К., Байрон Л. Ж. Выделение и изучение штаммов фосфатмобилизирующих микроорганизмов, перспективных для создания биоудобрения // Вестник Карагандинского университета. Серия: Биология. Медицина. География. 2020. Т. 99, № 3. С. 36–42.
  28. Чайковская Л. А., Мельничук,Т. Н., Каменева И. А., Баранская М. И., Овсиенко О. Л. Фосфатмобилизующий штамм почвенных бактерий Lelliottia nimipressuralis CCM 32-3 и биопрепарат на его основе для оптимизации минерального питания растений, стимуляции их роста и повышения урожайности. Патент РФ. RU 2676926 C1, 11.01.2019. Заявка № 2018100472 от 09.01.2018.
Received: 
21.02.2023
Accepted: 
03.03.2023
Published: 
30.06.2023
Short text (in English):
download
(downloads: 26)