solubility critical point

Phase equilibria and critical phenomena in cut 3 of the quaternary system water - pyridine - butyric acid - potassium chloride whose constituent ternary liquid system had a closed binodal curve were studied by means of the visual-polythermal method within 5-90°C. We have determined the temperature dependence of the solution composition corresponding to the critical solution point of the immis- cibility region.

Phase equilibria and critical phenomena in component mixtures of the cut 1 of the quaternary system Potassium Nitrate – Water – Pyridine – Butyric Аcid whose constituent ternary liquid system had a closed binodal curve were studied by means of the visualpolythermal method within 5–60oC. The volumes of two monotectic states in the composition tetrahedron have been found to be in contact via critical tie lines with increasing temperature.