Izvestiya of Saratov University.
ISSN 1816-9775 (Print)
ISSN 2541-8971 (Online)


equilibrium liquid – liquid – solid

Phase Equilibria and Salting Out of Butyric Acid in the Sodium Chloride – Water – Butyric Acid Ternary System

Phase equilibria in the water–butyric acid binary system in the range of ?10?0° C and in the sodium chloride–water–butyric acid ternary system in the range of 10.0?60.0° C were studied using the visual polythermal method. The phase diagram of the water–butyric acid binary system at ?9.5° C is characterized by eutectic equilibrium, the solid phases of which being ice and butyric acid crystals. The metastable delamination range was found on the ice crystallization field, bounded by a binodal curve with an upper critical solution temperature of ?3.7° C.