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Экспериментальное изучение растворимости гелия в пропан-2-оле при температурах 360, 420 и 480 к

Аннотация

Произведено экспериментальное изучение растворимости гелия в пропан-2-оле при высоких давлениях и температурах. Получены следующие значения констант Генри для раствора гелия в пропан-2-оле: 168,7 ± 6,3 МПа при 480 К, 341,2 ± 13,6 МПа при 420 К и 602,0 ± 43,5 МПа при 360 К.
 

DOI: 
10.18500/1816-9775-2017-17-2-155-162
Литература

1. Prausnitz J. M., Tavares F. W. Thermodynamics of fluid-phase equilibria for standard chemical engineering operations // AlChe J. 2004. Vol. 50, № 4. P. 739–761.
2. Skogestad S. Chemical and Energy Process Engineering. Boca-Raton : CRC Press, 2008. 440 p.
3. Nobandegani F. F., Gavahian M., Roeintan A. Modeling The Vapor-Liquid Equilibrium Of Mixtures Involving Noble Gases, Alkanes, and Refrigerants and Some Ionic Liquids Using Perturbed Hard-Sphere Equation of State // J. of Appl. Solut. Chem. and Modeling. 2013. Vol. 2, № 2. P. 85–95.
4. Sada E., Kito S., Ito Y. Solubility of Nitrous Oxide in the Mixtures of Alcohols and Water : Comparison with Pierotti’s Gas Solubility Theory // Industr. Engineer. Chem. Fundamentals. 1975. Vol. 14, № 3. P. 232–237.
5. Yamamoto H., Ichikawav K., Tokunaga J. Solubility of helium in methanol + water, ethanol + water, 1-propanol + + water, and 2-propanol + water solutions at 25 °C // J. of Chem. and Engineer. Data. 1994. Vol. 39, № 1. P. 155–157.
6. Windmann T., Linnemann M., Vrabec J. Fluid Phase Behavior of Nitrogen + Acetone and Oxygen + Acetone by Molecular Simulation, Experiment and the Peng– Robinson Equation of State // J. of Chem. and Engineer. Data. 2014. Vol. 59, № 1. P. 28–38.

7. Lemmon E. W., McLinden M. O., Wagner W. Thermodynamic Properties of Propane. III. A Reference Equation of State for Temperatures from the Melting Line to 650 K and Pressures up to 1000 MPa // J. of Chem. and Engineer. Data. 2009. Vol. 54, № 12. P. 3141–3180.
8. Span R., Wagner W. A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800 MPa // J. of Phys. and Chem. Ref. Data. 1996. Vol. 25, № 6. P. 1509–1596.
9. Ortiz Vega D. O. A New Wide Range Equation of State for Helium-4. Doctoral dissertation. College Station : Texas A & M University, 2013. 155 p. URL: http://hdl. handle.net/1969.1/151301.
10. Gross J., Sadowski G. Perturbed-Chain SAFT: An Equation of State Based on a Perturbation Theory for Chain Molecules // Industr. and Engineer. Chem. Res. 2001. Vol. 40, № 4. P. 1244–1260.
11. Al-Saifi N. M., Hamad E. Z., Englezos P. Prediction of vapor–liquid equilibrium in water–alcohol–hydrocarbon systems with the dipolar perturbed-chain SAFT equation of state // Fluid Phase Equilibria. 2008. Vol. 271, № 1–2. P. 82–93.
12. Dalton J. Essay II. On the force of steam or vapour from water and various other liquids, both in vacuum and in air // Memoirs of the Lit. and Philosoph. Soc. of Manchester. 1802. Vol. 5. P. 550–574.
13. Dalton J. Essay IV. On the expansion of elastic fluids by heat // Memoirs of the Lit. and Philos. Soc. of Manchester. 1802. Vol. 5. P. 595–602.
14. Raoult F.-M. Loi générale des tensions de vapeur des dissolvants // Comptes rendus hebdomadaires des sé- ances de l’Académie des sciences. 1887. Vol. 104. P. 1430–1433.
15. Henry W. Experiments on the quantity of gases absorbed by water, at different temperatures, and under different pressures // Philos. Transactions of the Royal Soc. of London. 1803. Vol. 93. P. 29–42, 274–276.
16. Adrain R. Research concerning the probabilities of the errors which happen in making observations // The Analyst; or Mathematical Museum. 1808. Vol. 1, № 4. P. 93–109.
17. Deiters U. K., Kraska T. High-Pressure Fluid Phase Equilibria: Phenomenology and Computation // Supercritical Fluid Science and Technology. Vol. 2. 1st ed. / ed. E. Kiran. Amsterdam : Elsevier BV, 2012. 370 p.

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